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Tác giả Hiromi Yamakawa
The modern theory of polymer solutions has depended on the advances made since the 1940s in the statistical mechanical theory of systems of simple molecules. The random-flight model, which was first investigated by Lord Rayleigh, can now be treated very conveniently
by the methods of Markoff and of Wang and Uhlenbeck. Specifically, the latter method has facilitated several advances in the theory of the excluded-volume effect. Except in an ideal state, now called the theta state, all equilibrium and nonequilibrium properties of dilute polymer solutions are influenced by the excluded-volume effect. A large part of this book is concerned with the excluded-volume effect.
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